A. Doug - Yes copper in boiler feedwater can cause problems. The boiler chemicals that are used are there to help form a magnetite coating on the boiler tubes and protect them from corrosion.
Copper in Boiler Feedwater - Corrosion engineering - Eng-Tips
Copper in Boiler Feedwater Copper in Boiler Feedwater GBurns (Mechanical) (OP) 19 Jun 03 14:38. I have long believed that elevated copper levels in feedwater is bad. What I am ignorant on is the damages that may result in boilers from 600 psig to 1500 psi.
Copper can be deposited on steel boiler surfaces during acid cleaning procedures if the cleaning programme is not controlled to ensure all the copper is complexed. Caustic corrosion can occur either as a result of steam blanketing (which allows salts to concentrate on boiler metal surfaces) or by localised boiling beneath porous deposits.
BOILER WATER TREATMENT FUNDAMENTALS.. - DieselShip
In boilers, the source of this corrosion could be dissolved gases in the boiler water or the excessive use of Hydrazine which will corrode Copper and Copper alloys, allowing Copper to be carried back to the boiler. Copper in the boiler displaces metal from the tube surfaces and plates out on the tubes.
Feedwater Chemistry Meets Stainless Steel, Copper, and Iron
Copper alloys containing nickel are far less susceptible to ammonia-induced SCC. Admiralty brass alloys have the additional concern of corrosion of zinc in the alloy due to low-pH conditions in the...
Water Handbook - Preboiler Industrial Boiler Corrosion.
The consensus is that feedwater oxygen, iron, and copper content should be very low (e.g., less than 7 ppb oxygen, 20 ppb iron, and 15 ppb copper for a 900 psig boiler) and that pH should be maintained between 8.5 and 9.5 for system corrosion protection.
Common Boiler Feedwater Treatment Issues and How to Avoid Them
When treating boiler feed water (the combination of boiler makeup and condensate return water), several issues can arise that cause boiler scaling, corrosion, fouling, and system failure. Below, we break down the most common boiler feed water issues and how to avoid them to help ensure system efficiency and operational safety.
Flow-Accelerated Corrosion: A Critical Issue Revisited.
OT cannot be used in systems that contain copper-alloy feedwater heater tubes, as copper corrosion would be much too severe. An issue that has come to light regarding OT programs is that of two.
BOILER WATER TREATMENT CHEMICALS AND ITS COMPOSITION
Inherent alkalinity helps maintain feed water alkalinity within parameters of 8.6 to 9.0. Used in boiler operating above 32 bar, will not readily react with O 2 below 50 o C hence risk of copper corrosion occurs with the ammonia stripping off the continuously reforming copper oxides. Supplied as a 35% solution; Carbohydrazide (N 2 H 3) 2 CO
(DOC) Boiler water treatment | Harmish Mistry - Academia.edu
The consensus is that feedwater oxygen, iron, and copper content should be very low (e.g., less than 7 ppb oxygen, 20 ppb iron, and 15 ppb copper for a 900 psig boiler) and that pH should be maintained between 8.5 and 9.5 for system corrosion protection. In order to minimize boiler system corrosion, an understanding of the operational requirements for all critical system components is.
Optimizing Pretreatment Key to Boiler Feedwater Quality.
Most high pressure boilers (>1000 PSIG) have a condensate polishing system to minimize problems associated with corrosion products (typically, iron and copper), and various process contaminants. Some process contaminants can cause severe boiler water chemistry upsets, and problems such as corrosion, foaming, and carryover to steam turbines.
How to Destroy a Boiler -- Part
2The undetected contamination of condensate returns is another common problem that leads to boiler feedwater contamination. Contaminants can vary from metals such as copper and iron to oils and process chemicals. Heavy metal contamination is usually a function of the construction materials of the process equipment and the condensate system. Oils and process chemicals are generally introduced.
Over a period of years, as the copper-based feedwater heaters failed, they were generally replaced down the line from the boiler with iron-based heaters, until only the very lowest pressure feedwater heaters and the condenser remained copper based. Because the remaining copper in the system remains in low- est pressure and temperature part of the pre-boiler system, sometimes the oxygen in the.
Plant Engineering | Maintaining boiler safety
Undetected contamination of condensate returns is another common problem, which leads to boiler feedwater contamination. Contaminants can vary from metals such as copper and iron, to oils and process chemicals. Heavy metal contamination is usually a function of the materials of construction of the process equipment and the condensate system.
Boiler Feedwater Treatment (Part I): Why Water Treatment is.
The feedwater (make-up water) from outside needs to be treated for the reduction or removal of impurities by first filtration, and then followed by softening, evaporation, deariation, ion exchange etc. Internal treatment is also required for the conditioning of impurities within the boiler system, to control corrosion, as reactions occur in the boiler itself and the steam pipelines.